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Sulfur — Native Sulfur From Russia

016Reactive nonmetal · Group 16 · Period 3

Sulfur

Sulfur (S) is element 16, a reactive nonmetal in the p-block — group 16, period 3. It is a solid at room temperature with 3 electron shells (2, 8, 6) and an atomic mass of 32.06 u.

Atomic mass
32.06 u
Phase · STP
solid
Melting
388 K · 115 °C
Boiling
718 K · 445 °C
Electronegativity
2.58
Density
2.07 g/cm³

Photograph — James St. John, CC BY 2.0 <https://creativecommons.org/licenses/by/2.0>, via Wikimedia Commons

Emission spectrum

The visible light Sulfur emits when energised — its unique spectral fingerprint.

Emission spectrum of Sulfur
Emission spectrum · via Wikimedia Commons

Identity

Atomic number
16
Standard atomic weight
32.06 u
Category
Reactive nonmetal
Group
16 · Chalcogens
Period
3
Block
p-block
Oxidation states
+6, +4, -2

Physical properties

Melting point
388 K · 115 °C
Boiling point
718 K · 445 °C
Density
2.07 g/cm³
Molar heat capacity
22.75 J/(mol·K)
Atomic radius
180 pm
Electron affinity
200.4101 kJ/mol

Atomic structure

S
16protons
16neutrons
16electrons
6valence e⁻
Noble-gas notation
[Ne] 3s2 3p4
Full configuration
1s2 2s2 2p6 3s2 3p4
Electrons per shell
2, 8, 6

Periodic trends

Where Sulfur ranks across all 118 elements.

Electronegativity2.58
Ionization energy999.6 kJ/mol
Electron affinity200.4101 kJ/mol
Density2.07 g/cm³
Atomic radius180 pm

Ionization energies

Energy to remove each successive electron (kJ/mol).

999.6
1
2.3k
2
3.4k
3
4.6k
4
7.0k
5
8.5k
6
27.1k
7
31.7k
8
36.6k
9
43.2k
10

Successive ionization energies (kJ/mol, log scale).

Discovery

Discovered
Ancient
Discovered by
Ancient china
Named by
Appearance
lemon yellow sintered microcrystals

Position in the table