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Chlorine — A Sample of Chlorine

017Reactive nonmetal · Group 17 · Period 3

Chlorine

Chlorine (Cl) is element 17, a reactive nonmetal in the p-block — group 17, period 3. It is a gas at room temperature with 3 electron shells (2, 8, 7) and an atomic mass of 35.45 u.

Atomic mass
35.45 u
Phase · STP
gas
Melting
172 K · -102 °C
Boiling
239 K · -34 °C
Electronegativity
3.16
Density
3.2 g/cm³

Photograph — Benjah-bmm27, Public domain, via Wikimedia Commons

Emission spectrum

The visible light Chlorine emits when energised — its unique spectral fingerprint.

Emission spectrum of Chlorine
Emission spectrum · via Wikimedia Commons

Identity

Atomic number
17
Standard atomic weight
35.45 u
Category
Reactive nonmetal
Group
17 · Halogens
Period
3
Block
p-block
Oxidation states
+7, +5, +1, -1

Physical properties

Melting point
172 K · -102 °C
Boiling point
239 K · -34 °C
Density
3.2 g/cm³
Molar heat capacity
Atomic radius
175 pm
Electron affinity
348.575 kJ/mol

Atomic structure

Cl
17protons
18neutrons
17electrons
7valence e⁻
Noble-gas notation
[Ne] 3s2 3p5
Full configuration
1s2 2s2 2p6 3s2 3p5
Electrons per shell
2, 8, 7

Periodic trends

Where Chlorine ranks across all 118 elements.

Electronegativity3.16
Ionization energy1251.2 kJ/mol
Electron affinity348.575 kJ/mol
Density3.2 g/cm³
Atomic radius175 pm

Ionization energies

Energy to remove each successive electron (kJ/mol).

1.3k
1
2.3k
2
3.8k
3
5.2k
4
6.5k
5
9.4k
6
11.0k
7
33.6k
8
38.6k
9
44.0k
10

Successive ionization energies (kJ/mol, log scale).

Discovery

Discovered
1774
Discovered by
Carl Wilhelm Scheele
Named by
Appearance
pale yellow-green gas

Position in the table